Increase in environmental pollution due fossil fuel exhaust emissions coupled with petroleum fuel depletion leads to search for the alternative green sources of energy. In views of this, methanolysis of gingerbread plum (Parinari macrophylla) seed oil had been carried out using 5wt.% MgO/Al2O3 catalyst to produce biodiesel and assess its fuel quality as a source of green energy. The results produced a biodiesel with 97% yields, 0.60g/cm3 density, 0.42% water and sediment content, 0.45mg/KOH acid value, 84.20mg/KOH saponification value, 75mg I2/100g Iodine value, 94.24 Cetane index and high heating value of 49MJ/Kg. The GC/MS results indicated the presence of methyl-9-octadecenoate, methyl-12-octadecenoate, methyl-hexadecanoate esters, octadecanoic and oleic acids. The methyl ester biodiesel produced therefore, promises to be a viable source of green energy for future use.
| Published in | American Journal of Environmental Protection (Volume 5, Issue 5) |
| DOI | 10.11648/j.ajep.20160505.14 |
| Page(s) | 128-133 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2016. Published by Science Publishing Group |
Parinari Macrophylla Seed Oil, Biodiesel and Transesterification
| [1] | Hong, I. K., Jeon G. S, Lee S. B., Prediction of biodiesel fuel properties from fatty acid alkyl ester, Journal of Industrial and Engineering Chemistry, (2014); 20 (4): 2348–2353 |
| [2] | Li H., Biller P., Hadavi S. A., Andrews G. E., Przybyla G. and Lea-Langton A., Assessing combustion and emission performance of direct use of SVO in a diesel engine by oxygen enrichment of intake air method, Biomass and Bioenergy, (2013); (51): 43–52 |
| [3] | Muciño, G. G. Romero, R.., Ramírez, A., Martínez, S. L., Baeza-Jiménez, R. and R. Natividad, Biodiesel production from used cooking oil and sea sand as heterogeneous catalyst, Fuel, (2014); 138: 143–148, http:// dx.doi.org/10.1016/j.fuel.2014.07.053 |
| [4] | Smith P. C., Ngothai Y., Nguyen, Q. D., O’Neill B. K., The addition of alkoxy side-chains to biodiesel and the impact on flow properties, Fuel, (2010); 89: 3517–3522 |
| [5] | Ahmed S., Hassan M. H., Abul Kalam M., Ashrafur Rahman S. M., Joynul Abedin M. and Shahir A., An experimental investigation of biodiesel production, characterization, engine performance, emission and noise of Brassica juncea methyl ester and its blends, Journal of Cleaner Production, (2014); 79: Pp. 74-81 |
| [6] | Fassinou W. F., Steene L. V., Toure S. and Martin E., what correlation is appropriate to evaluate biodiesels and vegetable oils higher heating value (HHV)?, Fuel, (2011); 90: 3398–340 |
| [7] | Can, Ö, Combustion characteristics, performance and exhaust emissions of a diesel engine fueled with a waste cooking oil biodiesel mixture, Energy Conversion and Management, (2014); 87: 676–686 |
| [8] | Dhar A., Kevin R. and Agarwal A. K., Production of biodiesel from high-FFA neem oil and its performance, emission and combustion characterization in a single cylinder DICI engine, Fuel Processing Technology, (2012); 97: Pp. 118–129 |
| [9] | Monteiro M. R., Ambrozin A. R. P., Lião L. M. and Ferreira A. G., Review Critical review on analytical methods for biodiesel characterization, Talanta, (2008); 77: 593–605 |
| [10] | Atabani, A. E. Silitonga A. S., Ong H. C., Mahlia T. M. I., Masjuki H. H., Badruddin I. A., Fayaz, H., Non-edible vegetable oils: Acritical evaluation of oilextraction, fatty acid compositions, biodieselproduction, characteristics, engine performance and emissions production, Renewable and Sustainable Energy Reviews, (2013); 18: 211–245 |
| [11] | Balat M., Potential alternatives to edible oils for biodiesel production–A review of current work. Energy Convers Manag, (2011); 52 (2): Pp. 1479–92 |
| [12] | Takase M., Zhao T., Zhang M., Chen Y., Liu H., Yang L., Wu X., An expatriate review of neem, jatropha, rubber and karanja as multipurpose non-edible biodiesel resources and comparison of their fuel, engine and emission properties, Renewable and Sustainable Energy Reviews, (2015): (43): Pp. 495–520 |
| [13] | Sorate K. A. and Bhale P. V., Biodiesel properties and automotive system compatibility issues, Energy Conversion and Management, (2011): 52, (8–9): Pp. 3034–3042 |
| [14] | Rashid, U., Anwar, F., Ashraf, M., Saleem, M. and Yusup, S.,, Application of response surface methodology for optimizing transesterification of Moringa oleifera oil: Biodiesel production, Energy Conversion and Management, (2011): 52: 3034–3042 |
| [15] | Amza, T., Balla, A., 1 Tounkara, F., Man, L. and Zhou, H. M., Effect of hydrolysis time on nutritional, functional and antioxidant properties of protein hydrolysates prepared from gingerbread plum (Neocarya macrophylla) seeds, International Food Research Journal, (2013): 20 (5): 2081-2090 |
| [16] | Warra AA, Umar RA, Sani I, Gafar MK, Nasiru A, and Ado A, Preliminary Phytochemical Screening and Physicochemical Analysis of Gingerbread plum (Parinari macrophylla) Seed Oil, Research and Reviews, Journal of Pharmacognosy and Phytochemistry, (2013): 1 (2): pp. 20-25 |
| [17] | Amza T., Amadou I., Kamara M. T., Zhu K. and Zhou H., Chemical and Nutrient Analysis of Gingerbread Plum (Neocarya macrophylla) Seeds, Advance Journal of Food Science and Technology, (2010): 2 (4): Pp. 191-195 |
| [18] | Borges, M. E. and Díaz, L., recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review, Renewable and Sustainable Energy Reviews, (2012): 16: Pp. 2839–2849 |
| [19] | Chouhan A. P. S., and Sarma A. K, Modern heterogeneous catalysts for biodiesel production: A comprehensive review, Renewable and Sustainable Energy Reviews, (2011): 15: Pp. 4378–4399 |
| [20] | Sharma Y. C., and Singh B. J., latest developments on application of heterogenous basic catalysts for an efficient and eco- friendly synthesis of biodiesel: A review, (2011): Fuel, 90 (4): Pp. 1309–1324 |
| [21] | Atadashi I. M., Aroua M. K., Abdul Aziz A. R., Sulaiman N. M. N., the effects of catalysts in biodiesel production: A review, Journal of Industrial and Engineering Chemistry, (2013): 19: 14–26 |
| [22] | Silitonga, A. S., Masjuki, H. H., Mahlia, T. M. I., Ong, H. C., Atabani, A. E., and Chong, W. T., A Global Comparative Review of Biodiesel Production from Jatropha Curcas Using Different Homogeneous Acid and Alkaline Catalysts: Study of Physical and Chemical properties, Renewable and Sustainable Energy Reviews., (2013): 24; Pp 514–533 |
| [23] | Abebe K. E, Yohannes K. and Rolando Z., Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO). Energy, (2011): 36: 2693-2700 |
| [24] | S. Puhan, N. Vedaraman, V. B, Boppana, G. Ram, Sankarnarayanan and Jeychendran, Mahua Oil (Madhuca indica Seed Oil) methyl ester as biodiesel: preparation and emission characteristics. Biomass and Bioenergy, (2005): 28: 87-93 |
| [25] | M. Mukhtar, C. Muhammad, M. U Dabai, M. Mamuda, Ethanolysis of Calabash (Lageneria sinceraria) Seed Oil for the Production of Biodiesel, American Journal of Energy Engineering., (2014): 2 (6): 141-145. doi: 10.11648/j.ajee.20140206.13 |
| [26] | Surfa Tech Corporation, (2009), Analytical methods, retrieved from: http://www.surfatech.com/pdfs /SurfaTech%20 Analytical%20 Methods.pdf |
| [27] | Demirbas A., Biofuel sources, biofuel policy, biofuel economy and global biofuel projection, Journal of energy conversion management, (2008): 49: 2106-2116 |
| [28] | Mohibbe, A., Amtul, W. and Nahar, N. M. Prospect and potential of Fatty acid methyl esters of some non-traditional seeds oils for use as biodiesel in india. Biomass bioener, (2005): 29: 293-302 |
| [29] | Galadima A Garba Z. N, Ibrahim, B. M, Homogeneous and heterogeneous trans- esterification of Groundnut oil for synthesizing Methyl Biodiesel int. Jor. P. App. Scis, (2008): 2 (3): 138-144 |
| [30] | Mustafa E. T, Jon H., V. Gerpen, and P. S. Wang, Fuel Property Effects on Injection Timing, Ignition Timing and Oxides of Nitrogen Emissions from Biodiesel-Fueled Engines, An ASAE/CSAE Meeting Presentation, Paper Number: 046081, Written for presentation at the 2004 ASAE/CSAE Annual International Meeting Sponsored by ASAE/CSAE Fairmont Chateau Laurier, The Westin, Government Centre Ottawa, Ontario, Canada, (2004): 1-4 |
| [31] | Filipović, I., Pikula, B., Bibić, D. and Kepnik, G., impact of physical properties of diesel and biodiesel mixture on characteristics of fuel spraying, ISSN 0350-350X GOMABN 52, 1, 16-28 Izvorni znanstveni rad / Original scientific paper, goriva i maziva, (2013): 52, 1: 16-28, 2013 |
| [32] | Bhuiya M. M. K, Rasul, M. G., Khan M. M. K., Ashwath N., Azad A. K., Hazrat M. A, Prospects of 2nd generation biodiesel as a sustainable fuel-Part 2: Properties, performance and emission characteristics, Renewable and Sustainable Energy Reviews.,(2016): 55: 1129–1146 |
| [33] | Gerpen, J. V, Shanks, B., Pruszko, P., Clements, D., and Knothe, G., biodiesel Analytical methods. Subcontractor Report, National Renewable Energy Laboratory, August 2002-January 2004. NREL/SR-510-36240, http://www.bentlybiofuels.com/pdfs/NREL_BD_Analytical.pdf accessed on 16/01/2012, (2004) |
| [34] | Meher, L. C., Vidya Sagar, D. and Naik, S. N., Technical Aspects of Biodiesel Production by Transesterification–A Review. Renew. Sust. Energ. Rev, (2006): 10: 248-268 |
| [35] | I. Barabás and I-A Todoruţ, Biodiesel Quality, Standards and Properties, Biodiesel Quality, Emissions and By-Products, Dr. Gisela Montero (Ed.), ISBN: 978-953-307-784-0, In Tech, Availablef rom: http://www.intechopen.com/books/biodiesel-quality-emissions-and-by-products/biodiesel-qualitystandards-and-properties, (2011) |
| [36] | ASTM D6751. Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels. West Conshohocken (PA): ASTM International; (2015) |
| [37] | O. M. Ali, R. Mamat, N. R. Abdullah, A. A. Abdullah, Analysis of blended fuel prope rties and engine perfor mance with palm biodies elediesel blended fuel, Renewable Energy, (2016); 86: 59-67 |
| [38] | Fernando S, kara P. Hernande R, Jha SK., effect of imcopletely converted soyabean oil on biodiesel quickly, Energy, (2007): 32, 844-851 |
| [39] | Atabani AE, Silitonga AS, Badruddin IA, Mahlia TMI, Masjuki HH, Mekhilef S., A comprehensive review on biodiesel as an alternative energy resource and its characteristics. Renew Sustain Energy Rev, (2012): 16: 2070–93 |
| [40] | Yaakob Z, Narayanan BN, Padikkaparambil S, Unni KS, Akbar PM. A review on the oxidation stability of biodiesel. Renew Sust Energy Rev (2014); 35: 136–53 |
| [41] | Bouaid A, Martinez M, Aracil J., Long storage stability of biodiesel from vegetable and used frying oils. Fuel, (2007): 86: 2596–602 |
| [42] | Pullen J. and Saeed K., an overvie w of biodiesel oxidation stability, Renewable and Sustainable Energy Reviews, (2012): 16: 5924–5950 |
| [43] | Knothe, G., Dependence of biodiseal fuel properties on the structure of fatty acid alkyl esters. Fuel processing technology, (2005): 86, 1058-1070 |
| [44] | J. Fu, S. Q. Turn, B. M. Takushi, C. L. Kawamata, Storage and oxidation stabilities of biodiesel derived from waste cooking oil, Fuel, (2016): 167: 89–97 |
| [45] | Park, T. Y., Kim, D. K., Lee, J. P. Park, S. C., Kim, Y. J., Lee, J. S., Blending effect of biodiesels on oxidation stability and low temperature flow properties. Biores. Technol., (2008): 99: 1196-1203 |
| [46] | Sokoto M. A., Hassan L. G., Dangoggo S. M., Ahmad H. G. And Uba A., Influence of fatty acid methyl ester on fuel properties of biodiesel produced from the seed oil of Curcubita Pepo (Kabushi), Nigerian Journal of Basic and Applied Science (2011): 19 (1): 81- 86 |
| [47] | Bamgboye, A. I and Hansen, A. C, Prediction of cetane number of biodiesel fuel from the fatty acid methyl ester composition. Int. J. Agrophy., (2008): 22: 21-29 |
| [48] | Gülüm, M. and Bilgin, A., Density, flash point and heating value variations of corn oil biodiesel– diesel fuel blends, Fuel Processing Technology, (2015): 134: 456–464 |
| [49] | Demirbas A., calculation of higher heating value of biomass fuels. Fuel, (1997): 76: 431-434 |
| [50] | Graboski MS. and Mc Cormick RL., Combustion of fat and vegetables oil fuels in diesel engines. Prog energy combust sci., (1998): 24: 125-64 |
| [51] | Srivastava A. and Prased R., Triglycerides based diesel fuels. Renewable and Sustainable energy Review, (2000): 4: 111-133 |
| [52] | Oliveira LE, Da Silva M. (2013), Comparative study of calorific value of rapeseed, soybean, jatropha curcas and crambe biodiesel. International Conference on Renewable Energies and Power Quality (ICREPQ’13) Bilbao (Spain), 20-22 March, 2013 |
| [53] | Wan Ghazali W N M., Mamat, R., Masjuki, H. H. and Najafi G., Effects of biodiesel from different feedstocks on engine performance and emissions: A review, Renewable and Sustainable Energy Reviews, (2015): 51: 585–602 |
| [54] | Verma, P., Sharma M. P. and Dwivedi, G., Impact of alcohol on biodiesel production and properties, Renewable and Sustainable Energy Reviews, (2016): 56: 319–333 |
| [55] | Dwivedi G, Sharma MP., Potential and limitation of straight vegetable oils as engine fuel – an Indian perspective. Renew Sustain Energy Rev, (2014): 33: 316–322 |
APA Style
Muhammad Mukhtar, Musa Usman Dabai. (2016). Production and Fuel Properties of Biodiesel from Gingerbread Plum (Parinari macrophylla) Seed Oil Using MgO/Al2O3 Catalyst. American Journal of Environmental Protection, 5(5), 128-133. https://doi.org/10.11648/j.ajep.20160505.14
ACS Style
Muhammad Mukhtar; Musa Usman Dabai. Production and Fuel Properties of Biodiesel from Gingerbread Plum (Parinari macrophylla) Seed Oil Using MgO/Al2O3 Catalyst. Am. J. Environ. Prot. 2016, 5(5), 128-133. doi: 10.11648/j.ajep.20160505.14
AMA Style
Muhammad Mukhtar, Musa Usman Dabai. Production and Fuel Properties of Biodiesel from Gingerbread Plum (Parinari macrophylla) Seed Oil Using MgO/Al2O3 Catalyst. Am J Environ Prot. 2016;5(5):128-133. doi: 10.11648/j.ajep.20160505.14
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Download@article{10.11648/j.ajep.20160505.14,
author = {Muhammad Mukhtar and Musa Usman Dabai},
title = {Production and Fuel Properties of Biodiesel from Gingerbread Plum (Parinari macrophylla) Seed Oil Using MgO/Al2O3 Catalyst},
journal = {American Journal of Environmental Protection},
volume = {5},
number = {5},
pages = {128-133},
doi = {10.11648/j.ajep.20160505.14},
url = {https://doi.org/10.11648/j.ajep.20160505.14},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajep.20160505.14},
abstract = {Increase in environmental pollution due fossil fuel exhaust emissions coupled with petroleum fuel depletion leads to search for the alternative green sources of energy. In views of this, methanolysis of gingerbread plum (Parinari macrophylla) seed oil had been carried out using 5wt.% MgO/Al2O3 catalyst to produce biodiesel and assess its fuel quality as a source of green energy. The results produced a biodiesel with 97% yields, 0.60g/cm3 density, 0.42% water and sediment content, 0.45mg/KOH acid value, 84.20mg/KOH saponification value, 75mg I2/100g Iodine value, 94.24 Cetane index and high heating value of 49MJ/Kg. The GC/MS results indicated the presence of methyl-9-octadecenoate, methyl-12-octadecenoate, methyl-hexadecanoate esters, octadecanoic and oleic acids. The methyl ester biodiesel produced therefore, promises to be a viable source of green energy for future use.},
year = {2016}
}
TY - JOUR T1 - Production and Fuel Properties of Biodiesel from Gingerbread Plum (Parinari macrophylla) Seed Oil Using MgO/Al2O3 Catalyst AU - Muhammad Mukhtar AU - Musa Usman Dabai Y1 - 2016/09/12 PY - 2016 N1 - https://doi.org/10.11648/j.ajep.20160505.14 DO - 10.11648/j.ajep.20160505.14 T2 - American Journal of Environmental Protection JF - American Journal of Environmental Protection JO - American Journal of Environmental Protection SP - 128 EP - 133 PB - Science Publishing Group SN - 2328-5699 UR - https://doi.org/10.11648/j.ajep.20160505.14 AB - Increase in environmental pollution due fossil fuel exhaust emissions coupled with petroleum fuel depletion leads to search for the alternative green sources of energy. In views of this, methanolysis of gingerbread plum (Parinari macrophylla) seed oil had been carried out using 5wt.% MgO/Al2O3 catalyst to produce biodiesel and assess its fuel quality as a source of green energy. The results produced a biodiesel with 97% yields, 0.60g/cm3 density, 0.42% water and sediment content, 0.45mg/KOH acid value, 84.20mg/KOH saponification value, 75mg I2/100g Iodine value, 94.24 Cetane index and high heating value of 49MJ/Kg. The GC/MS results indicated the presence of methyl-9-octadecenoate, methyl-12-octadecenoate, methyl-hexadecanoate esters, octadecanoic and oleic acids. The methyl ester biodiesel produced therefore, promises to be a viable source of green energy for future use. VL - 5 IS - 5 ER -
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