In an attempt to check the effect of the transition metal ions on the glass network, the following chemical formula was used to prepare some of Iron sodium phosphate glasses doped with different transition metal (TM) ions. 50 mol% P2O5 + 20 mol% Na2O + 15 mol% Fe2O3 + 15 mol% MnOm, where MnOm represents V2O5, MnO, Co3O4, CuO and ZnO. Mossbauer Effect (ME) spectroscopic analysis showed that, the iron ions are located in two different oxidation states Fe3+ and Fe2+. A fraction of Fe3+ ions act as glass network formers (GNFs), whereas the other in addition to all Fe2+ ions act as glass network modifiers (GNMs). The electrical properties for all samples have been measured and then studied as a function of the TMIs atomic number. The D.C. conductivity showed a gradual decreasing with increasing the atomic number of TMIs, while the A.C. conductivity has a similar behavior as predicted by CBH model.
| Published in | International Journal of High Energy Physics (Volume 4, Issue 6) |
| DOI | 10.11648/j.ijhep.20170406.12 |
| Page(s) | 75-87 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
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Copyright © The Author(s), 2017. Published by Science Publishing Group |
Transition Metal Ions, Mossbauer Effect, Amorphous Materials, Structural Properties and Electrical Properties
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APA Style
Hossam Mohamed Gomaa, Ahmed Hamdy El-Dosokey, Khaled Hamoda Idress. (2017). (FeNaP)2O9 Glasses Doped with Different TM Ions. International Journal of High Energy Physics, 4(6), 75-87. https://doi.org/10.11648/j.ijhep.20170406.12
ACS Style
Hossam Mohamed Gomaa; Ahmed Hamdy El-Dosokey; Khaled Hamoda Idress. (FeNaP)2O9 Glasses Doped with Different TM Ions. Int. J. High Energy Phys. 2017, 4(6), 75-87. doi: 10.11648/j.ijhep.20170406.12
AMA Style
Hossam Mohamed Gomaa, Ahmed Hamdy El-Dosokey, Khaled Hamoda Idress. (FeNaP)2O9 Glasses Doped with Different TM Ions. Int J High Energy Phys. 2017;4(6):75-87. doi: 10.11648/j.ijhep.20170406.12
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Download@article{10.11648/j.ijhep.20170406.12,
author = {Hossam Mohamed Gomaa and Ahmed Hamdy El-Dosokey and Khaled Hamoda Idress},
title = {(FeNaP)2O9 Glasses Doped with Different TM Ions},
journal = {International Journal of High Energy Physics},
volume = {4},
number = {6},
pages = {75-87},
doi = {10.11648/j.ijhep.20170406.12},
url = {https://doi.org/10.11648/j.ijhep.20170406.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijhep.20170406.12},
abstract = {In an attempt to check the effect of the transition metal ions on the glass network, the following chemical formula was used to prepare some of Iron sodium phosphate glasses doped with different transition metal (TM) ions. 50 mol% P2O5 + 20 mol% Na2O + 15 mol% Fe2O3 + 15 mol% MnOm, where MnOm represents V2O5, MnO, Co3O4, CuO and ZnO. Mossbauer Effect (ME) spectroscopic analysis showed that, the iron ions are located in two different oxidation states Fe3+ and Fe2+. A fraction of Fe3+ ions act as glass network formers (GNFs), whereas the other in addition to all Fe2+ ions act as glass network modifiers (GNMs). The electrical properties for all samples have been measured and then studied as a function of the TMIs atomic number. The D.C. conductivity showed a gradual decreasing with increasing the atomic number of TMIs, while the A.C. conductivity has a similar behavior as predicted by CBH model.},
year = {2017}
}
TY - JOUR T1 - (FeNaP)2O9 Glasses Doped with Different TM Ions AU - Hossam Mohamed Gomaa AU - Ahmed Hamdy El-Dosokey AU - Khaled Hamoda Idress Y1 - 2017/11/27 PY - 2017 N1 - https://doi.org/10.11648/j.ijhep.20170406.12 DO - 10.11648/j.ijhep.20170406.12 T2 - International Journal of High Energy Physics JF - International Journal of High Energy Physics JO - International Journal of High Energy Physics SP - 75 EP - 87 PB - Science Publishing Group SN - 2376-7448 UR - https://doi.org/10.11648/j.ijhep.20170406.12 AB - In an attempt to check the effect of the transition metal ions on the glass network, the following chemical formula was used to prepare some of Iron sodium phosphate glasses doped with different transition metal (TM) ions. 50 mol% P2O5 + 20 mol% Na2O + 15 mol% Fe2O3 + 15 mol% MnOm, where MnOm represents V2O5, MnO, Co3O4, CuO and ZnO. Mossbauer Effect (ME) spectroscopic analysis showed that, the iron ions are located in two different oxidation states Fe3+ and Fe2+. A fraction of Fe3+ ions act as glass network formers (GNFs), whereas the other in addition to all Fe2+ ions act as glass network modifiers (GNMs). The electrical properties for all samples have been measured and then studied as a function of the TMIs atomic number. The D.C. conductivity showed a gradual decreasing with increasing the atomic number of TMIs, while the A.C. conductivity has a similar behavior as predicted by CBH model. VL - 4 IS - 6 ER -
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