Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction

Yusuke Sano; Ryoko Nakano; Hiroshi Sekiguchi; Shigeru Yao

doi:doi:10.11648/j.ijmsa.20140306.28

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Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction

Yusuke Sano, Ryoko Nakano, Hiroshi Sekiguchi, Shigeru Yao

Published in International Journal of Materials Science and Applications (Volume 3, Issue 6)

Received: 25 November 2014 Accepted: 4 December 2014 Published: 16 December 2014

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Abstract

Side-Chain Crystalline Block Co-Polymer (SCCBC), which is composed of a side-chain crystalline monomer unit and a functional monomer unit (which can confer solvent-compatibility, polarity, etc.), can be adsorbed to a polyethylene crystal through crystalline supramolecular interaction. By using this interaction, we can modify not only the surface but also the inner pores of a porous polyethylene membrane to give various properties. In this study, we used a monomer with ethylene oxide repeating units as a functional unit, and evaluated its potential as a solid electrolyte for use in a Li ion secondary battery. The properties of the solid electrolyte were excellent compared to those of a non-modified porous membrane at low temperature. In addition, the solid electrolyte did not show temperature-dependence, and the Li+ ion conductivity remained nearly constant throughout the temperature range of 30°C to 60 ºC. However, at high temperature (above 70 ºC), the conductivity began to decrease. This characteristic may make it useful for sensing temperature and for self-controlling thermal runaway.

Published in	International Journal of Materials Science and Applications (Volume 3, Issue 6)
DOI	10.11648/j.ijmsa.20140306.28
Page(s)	399-403
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Solid Electrolyte, Side-Chain Crystalline Block Co-Polymer, Crystalline Supramolecular Interaction, Filling Membrane

References

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[2]	K. Inomata, Y. Sakamaki, T. Nose, S. Sasaki, “Solid-State Structure of Comb-Like Polymers Having n-Octadecyl Side Chains I. Cocrystallization of Side Chain with n-Octadecanoic Acid,” Polym. J., vol. 28, 1996, pp. 986-991.
[3]	Y. Inoue, M. Matsui, S. Kuroki, I. Ando, “A study of diffusional behavior of polymer having semiflexible main-chain with long n-alkyl side-chains as associated with structural behavior of the side-chains,” J. Mol. Struct., vol. 976, 2010, pp. 141-149.
[4]	T. Okuma, S. Yao, R. Nakano, H. Sekiguchi, S. Ichikawa, D. Tatsumi, “Supramolecular function of side chain crystalline block co-polymer -Dispersant effect of concentrated polyethylene particle dispersion and thermal rheological effect-,” IEICE Technical Report, vol. 113/167, 2013, pp. 81-82.
[5]	S. Yao, T. Okuma, C. Kumamaru, H. Sekiguchi, S. Ichikawa, D. Tatsumi, “Supramolecular Interaction of Side-Chain Crystalline Block Co-Polymer and Its Thermal Rheological Function,” Mater. Trans. vol. 54, 2013, pp. 1381-1384.
[6]	S. Yao, M. Sakurai, H. Sekiguchi, H. Otsubo, T. Uto, Y. Yamachika, W. Ishino, S. Ichikawa, D. Tatsumi, “Thermal Rheological Fluid Properties of Particle Dispersion Systems using Side Chain Crystalline Block Copolymer (III),” Nihon Reoroji Gakkaishi (J. Soc. Rheol. Japan), vol. 41, 2013, pp. 7-12.
[7]	S. Yao, M. Sakurai, H. Sekiguchi, H. Otsubo, T. Uto, Y. Yamachika, W. Ishino, S. Ichikawa, D. Tatsumi, “The Intelligent Material Function of Side Chain Crystalline Block Copolymer (IV). Control the Lithium Ion Mobility in Polyethylene Porous Membrane,” Nihon Reoroji Gakkaishi (J. Soc. Rheol. Japan), vol. 40, 2012, pp. 253-256.
[8]	S. Ichikawa, S. Yao, “Thermal Rheological Properties of the Particle Dispersion Sysytems with Using Side Chain Crystalline Block Co-Polymer II,” Nihon Reoroji Gakkaishi (J. Soc. Rheol. Japan), vol. 40, 2012, pp. 37-40.
[9]	S. Yao, S. Ichikawa, “A Nobel Dispersant for High Content Polyethylene Particle Dispersion,” Nihon Reoroji Gakkaishi (J. Soc. Rheol. Japan) , vol. 39, 2011, pp. 181-182

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APA Style

Yusuke Sano, Ryoko Nakano, Hiroshi Sekiguchi, Shigeru Yao. (2014). Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction. International Journal of Materials Science and Applications, 3(6), 399-403. https://doi.org/10.11648/j.ijmsa.20140306.28

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ACS Style

Yusuke Sano; Ryoko Nakano; Hiroshi Sekiguchi; Shigeru Yao. Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction. Int. J. Mater. Sci. Appl. 2014, 3(6), 399-403. doi: 10.11648/j.ijmsa.20140306.28

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AMA Style

Yusuke Sano, Ryoko Nakano, Hiroshi Sekiguchi, Shigeru Yao. Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction. Int J Mater Sci Appl. 2014;3(6):399-403. doi: 10.11648/j.ijmsa.20140306.28

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@article{10.11648/j.ijmsa.20140306.28,
  author = {Yusuke Sano and Ryoko Nakano and Hiroshi Sekiguchi and Shigeru Yao},
  title = {Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction},
  journal = {International Journal of Materials Science and Applications},
  volume = {3},
  number = {6},
  pages = {399-403},
  doi = {10.11648/j.ijmsa.20140306.28},
  url = {https://doi.org/10.11648/j.ijmsa.20140306.28},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20140306.28},
  abstract = {Side-Chain Crystalline Block Co-Polymer (SCCBC), which is composed of a side-chain crystalline monomer unit and a functional monomer unit (which can confer solvent-compatibility, polarity, etc.), can be adsorbed to a polyethylene crystal through crystalline supramolecular interaction. By using this interaction, we can modify not only the surface but also the inner pores of a porous polyethylene membrane to give various properties. In this study, we used a monomer with ethylene oxide repeating units as a functional unit, and evaluated its potential as a solid electrolyte for use in a Li ion secondary battery. The properties of the solid electrolyte were excellent compared to those of a non-modified porous membrane at low temperature. In addition, the solid electrolyte did not show temperature-dependence, and the Li+ ion conductivity remained nearly constant throughout the temperature range of 30°C to 60 ºC. However, at high temperature (above 70 ºC), the conductivity began to decrease.  This characteristic may make it useful for sensing temperature and for self-controlling thermal runaway.},
 year = {2014}
}

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TY  - JOUR
T1  - Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction
AU  - Yusuke Sano
AU  - Ryoko Nakano
AU  - Hiroshi Sekiguchi
AU  - Shigeru Yao
Y1  - 2014/12/16
PY  - 2014
N1  - https://doi.org/10.11648/j.ijmsa.20140306.28
DO  - 10.11648/j.ijmsa.20140306.28
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 399
EP  - 403
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20140306.28
AB  - Side-Chain Crystalline Block Co-Polymer (SCCBC), which is composed of a side-chain crystalline monomer unit and a functional monomer unit (which can confer solvent-compatibility, polarity, etc.), can be adsorbed to a polyethylene crystal through crystalline supramolecular interaction. By using this interaction, we can modify not only the surface but also the inner pores of a porous polyethylene membrane to give various properties. In this study, we used a monomer with ethylene oxide repeating units as a functional unit, and evaluated its potential as a solid electrolyte for use in a Li ion secondary battery. The properties of the solid electrolyte were excellent compared to those of a non-modified porous membrane at low temperature. In addition, the solid electrolyte did not show temperature-dependence, and the Li+ ion conductivity remained nearly constant throughout the temperature range of 30°C to 60 ºC. However, at high temperature (above 70 ºC), the conductivity began to decrease.  This characteristic may make it useful for sensing temperature and for self-controlling thermal runaway.
VL  - 3
IS  - 6
ER  -

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Author Information

Yusuke Sano

Dept. of Chemical Engineering, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka, Japan, 814-0180
Ryoko Nakano

Dept. of Chemical Engineering, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka, Japan, 814-0180
Hiroshi Sekiguchi

Dept. of Chemical Engineering, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka, Japan, 814-0180
Shigeru Yao

Dept. of Chemical Engineering, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka, Japan, 814-0180

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Plain Text BibTeX RIS

APA Style

Yusuke Sano, Ryoko Nakano, Hiroshi Sekiguchi, Shigeru Yao. (2014). Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction. International Journal of Materials Science and Applications, 3(6), 399-403. https://doi.org/10.11648/j.ijmsa.20140306.28

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ACS Style

Yusuke Sano; Ryoko Nakano; Hiroshi Sekiguchi; Shigeru Yao. Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction. Int. J. Mater. Sci. Appl. 2014, 3(6), 399-403. doi: 10.11648/j.ijmsa.20140306.28

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AMA Style

Yusuke Sano, Ryoko Nakano, Hiroshi Sekiguchi, Shigeru Yao. Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction. Int J Mater Sci Appl. 2014;3(6):399-403. doi: 10.11648/j.ijmsa.20140306.28

Copy | Download

@article{10.11648/j.ijmsa.20140306.28,
  author = {Yusuke Sano and Ryoko Nakano and Hiroshi Sekiguchi and Shigeru Yao},
  title = {Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction},
  journal = {International Journal of Materials Science and Applications},
  volume = {3},
  number = {6},
  pages = {399-403},
  doi = {10.11648/j.ijmsa.20140306.28},
  url = {https://doi.org/10.11648/j.ijmsa.20140306.28},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20140306.28},
  abstract = {Side-Chain Crystalline Block Co-Polymer (SCCBC), which is composed of a side-chain crystalline monomer unit and a functional monomer unit (which can confer solvent-compatibility, polarity, etc.), can be adsorbed to a polyethylene crystal through crystalline supramolecular interaction. By using this interaction, we can modify not only the surface but also the inner pores of a porous polyethylene membrane to give various properties. In this study, we used a monomer with ethylene oxide repeating units as a functional unit, and evaluated its potential as a solid electrolyte for use in a Li ion secondary battery. The properties of the solid electrolyte were excellent compared to those of a non-modified porous membrane at low temperature. In addition, the solid electrolyte did not show temperature-dependence, and the Li+ ion conductivity remained nearly constant throughout the temperature range of 30°C to 60 ºC. However, at high temperature (above 70 ºC), the conductivity began to decrease.  This characteristic may make it useful for sensing temperature and for self-controlling thermal runaway.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Solid Electrolyte Function of a Polyethylene Porous Membrane Filled with Side-Chain Crystalline Block Co-Polymer by Using Its Crystalline Supramolecular Interaction
AU  - Yusuke Sano
AU  - Ryoko Nakano
AU  - Hiroshi Sekiguchi
AU  - Shigeru Yao
Y1  - 2014/12/16
PY  - 2014
N1  - https://doi.org/10.11648/j.ijmsa.20140306.28
DO  - 10.11648/j.ijmsa.20140306.28
T2  - International Journal of Materials Science and Applications
JF  - International Journal of Materials Science and Applications
JO  - International Journal of Materials Science and Applications
SP  - 399
EP  - 403
PB  - Science Publishing Group
SN  - 2327-2643
UR  - https://doi.org/10.11648/j.ijmsa.20140306.28
AB  - Side-Chain Crystalline Block Co-Polymer (SCCBC), which is composed of a side-chain crystalline monomer unit and a functional monomer unit (which can confer solvent-compatibility, polarity, etc.), can be adsorbed to a polyethylene crystal through crystalline supramolecular interaction. By using this interaction, we can modify not only the surface but also the inner pores of a porous polyethylene membrane to give various properties. In this study, we used a monomer with ethylene oxide repeating units as a functional unit, and evaluated its potential as a solid electrolyte for use in a Li ion secondary battery. The properties of the solid electrolyte were excellent compared to those of a non-modified porous membrane at low temperature. In addition, the solid electrolyte did not show temperature-dependence, and the Li+ ion conductivity remained nearly constant throughout the temperature range of 30°C to 60 ºC. However, at high temperature (above 70 ºC), the conductivity began to decrease.  This characteristic may make it useful for sensing temperature and for self-controlling thermal runaway.
VL  - 3
IS  - 6
ER  -

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