Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice

Mauricio Guilherme Vieira; Gabriel de Souza; Gilberto Henrique Bardini Aristides; Larissa Voleck Lopes; Angélica Machi Lazarin

doi:doi:10.11648/j.ijssn.20170502.12

Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice

Mauricio Guilherme Vieira, Gabriel de Souza, Gilberto Henrique Bardini Aristides, Larissa Voleck Lopes, Angélica Machi Lazarin

Published in International Journal of Sensors and Sensor Networks (Volume 5, Issue 2)

Received: 9 June 2017 Accepted: 27 June 2017 Published: 20 July 2017

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

The chemically modified silica gel with 3-aminopropyltrimethoxysilane groups and EDTA was used to immobilize ruthenium complex initially. These materials were incorporated into a carbon paste electrode and its electrochemical properties were investigated. However, for ascorbic acid solution, an enhancement of the anodic peak current was detected due to electrocatalytic oxidation. The electrodes presented good repeatability, stability and reproducible. The sensors were applied in ascorbic acid determination in industrial fruit juice with success.

Published in	International Journal of Sensors and Sensor Networks (Volume 5, Issue 2)
DOI	10.11648/j.ijssn.20170502.12
Page(s)	27-33
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Silica Gel, 3-Aminopropyltrimethoxysilane, Carbon Paste Electrode, Ruthenium Complex, Ascorbic Acid

References

[1]	Sotomayor M D P T, Kubota L T (2002) Enzymeless biosensors: A novel area for the development of amperometric sensors. Quim Nova 25: 123-128.
[2]	Iler R K (1979) The Chemistry of Silica, John Wiley & Sons, New York.
[3]	Gil E S, Melo G R (2010) Electrochemical biosensors in pharmaceutical analysis. Bras J Pharm Sci 46: 375-391.
[4]	Ping J, Wu J, Ying Y, Wang M, Liu G, Zhang M (2011) Evaluation of Trace Heavy Metal Levels in Soil Samples Using an Ionic Liquid Modified Carbon Paste Electrode. J Agric Food Chem 59: 4418–4423.
[5]	Ping J, Ru S, Fan K, Wu J, Ying Y (2010) Copper oxide nanoparticles and ionic liquid modified carbon electrode for the non-enzymatic electrochemical sensing of hydrogen peroxide. Microchim Acta 171:117–123.
[6]	Vancara I, Vytřas K, Barek J, Zima J (2001) Carbon paste electrodes in modern electroanalysis. Crit Rev Anal Chem 31: 311–345.
[7]	Raj C. R, Ohsaka T (2001) Electroanalysis of ascorbate and dopamine at a gold electrode modified with a positively charged self-assembled monolayer. J Electroanal Chem 496: 44-49.
[8]	Carmo D R, Paim L L (2013) Investigation about the copper adsorption on the chloropropylsilica gel surface modified with a nanostructured dendrimer DAB-Am-16: an analytical application for determination of copper in different samples. Mater Res 16: 164-172.
[9]	Alothmanand A Z, Apblett W A (2010) Metal ion adsorption using polyamine-functionalized mesoporous materials prepared from bromopropyl-functionalized mesoporous silica. J Hazard Mater 182: 581-590.
[10]	Lazarin A M, Sernaglia R L (2014) Spectrophotometric Characterization of the Complex Generated in Solution for the Reaction of H[Ru(III)Cl₂(H₂EDTA)] Complex with AETS Modifier Agent. Open J. Synthesis Theory and Applications 3: 37-43.
[11]	Molaakbar E, Mostafavi A, Beitollani H, Alizadeh R (014) Synthesis of ZnO nanorods and their application in the construction of a nanostructure-based electrochemical sensor for determination of levodopa in the presence of carbidopa. Analyst 139: 4356-4364.
[12]	Beitollahi H, Tajik S, Jahani S (2016) Electrocatalytic Determination of Hydrazine and Phenol Using a Carbon Paste Electrode Modified with Ionic Liquids and Magnetic Core-shell Fe₃O₄@SiO₂/MWCNT Nanocomposite. Electroanalysis 28: 1093–1099.
[13]	Beitollahi H, Gholami A, Ganjali M R (2015) Preparation, characterization and electrochemical application of Ag–ZnO nanoplates for voltammetric determination of glutathione and tryptophan using modified carbon paste electrode. Mater Sci Eng C 57: 107–112.
[14]	Beitollahi H, Kekooei S (2016) Application of a Modified CuO Nanoparticles Carbon Paste Electrode for Simultaneous Determination of Isoperenaline, Acetaminophen and N-acetyl-L-cysteine. Electroanalysis 28: 645–653.
[15]	Beitollahi H, Ivari S G, Torkzadeh-Mahani M (2016) Voltammetric determination of 6-thioguanine and folic acid using a carbon paste electrode modified with ZnO-CuO nanoplates and modifier. Mater Sci Eng C Mater Biol Appl 69: 128–133.
[16]	Beitollahi H, Ebadinejad F, Shojaie F, Torkzadeh-Mahani M (2016) A magnetic core–shell Fe₃O₄@SiO₂/MWCNT nanocomposite modified carbon paste electrode for amplified electrochemical sensing of amlodipine and hydrochlorothiazide. Anal Methods 8: 6185-6193.
[17]	Hacisevki A (2009) An overview of ascorbic acid biochemistry. J Fac Pharm 38: 233-255.
[18]	Du J, Cullen J J, Buettner G R (2012) Ascorbic acid: Chemistry, biology and the treatment of cancer. Biochim Biophys Acta 1826: 443-457.
[19]	Chambial S, Dwivedi S, Shukla K K, Jhon P J, Sharma P (2013) Vitamin C in disease prevention and cure: An overview. Indian J Clin Biochem 28: 314-328.
[20]	Filippov A P (19984) Model of reactions of complex formation by metal salts with electrically neutral ligands grafted to a surface. Theor Exp Chem 19: 427-433.
[21]	Bard A J, Faulkner L R (1980) “in Electrochemical Methods, Fundamentals and Applications” Wiley & Sons, New York, pp. 218.
[22]	Cazula B B, Lazarin A M (2017) Development of chemically modified carbon paste electrodes with transition metal complexes anchored on silica gel. Mater Chem Phys 186: 470-477.
[23]	Kubota L T, Gushikem Y, Perez J, Tanaka A A (1995) Electrochemical properties of iron phthalocyanine immobilized on titanium (IV) oxide coated on silica gel surface. Langmuir 11: 1009-1013.
[24]	Zaldivar G A P, Gushikem Y (1992) Thin (IV) oxide grafied on a sílica gel surface as a conducting substrate base for nickel hexacyanoferrate. J Electroanal Chem 337: 165-174.
[25]	Panice L B, Oliveira E A, Molin Filho R A D, Oliveira D P, Lazarin A M, Andreotti E I S, Sernaglia R L, Gushikem Y (2014) Electrochemical properties of the hexacyanoferrate (II)-ruthenium (III) complex immobilized on silica gel surface chemically modified with zirconium (IV) oxide. Mater Sci Eng B 188: 78-83.

Cite This Article

Plain Text BibTeX RIS

APA Style

Mauricio Guilherme Vieira, Gabriel de Souza, Gilberto Henrique Bardini Aristides, Larissa Voleck Lopes, Angélica Machi Lazarin. (2017). Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice. International Journal of Sensors and Sensor Networks, 5(2), 27-33. https://doi.org/10.11648/j.ijssn.20170502.12

Copy | Download

ACS Style

Mauricio Guilherme Vieira; Gabriel de Souza; Gilberto Henrique Bardini Aristides; Larissa Voleck Lopes; Angélica Machi Lazarin. Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice. Int. J. Sens. Sens. Netw. 2017, 5(2), 27-33. doi: 10.11648/j.ijssn.20170502.12

Copy | Download

AMA Style

Mauricio Guilherme Vieira, Gabriel de Souza, Gilberto Henrique Bardini Aristides, Larissa Voleck Lopes, Angélica Machi Lazarin. Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice. Int J Sens Sens Netw. 2017;5(2):27-33. doi: 10.11648/j.ijssn.20170502.12

Copy | Download

@article{10.11648/j.ijssn.20170502.12,
  author = {Mauricio Guilherme Vieira and Gabriel de Souza and Gilberto Henrique Bardini Aristides and Larissa Voleck Lopes and Angélica Machi Lazarin},
  title = {Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice},
  journal = {International Journal of Sensors and Sensor Networks},
  volume = {5},
  number = {2},
  pages = {27-33},
  doi = {10.11648/j.ijssn.20170502.12},
  url = {https://doi.org/10.11648/j.ijssn.20170502.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijssn.20170502.12},
  abstract = {The chemically modified silica gel with 3-aminopropyltrimethoxysilane groups and EDTA was used to immobilize ruthenium complex initially. These materials were incorporated into a carbon paste electrode and its electrochemical properties were investigated. However, for ascorbic acid solution, an enhancement of the anodic peak current was detected due to electrocatalytic oxidation. The electrodes presented good repeatability, stability and reproducible. The sensors were applied in ascorbic acid determination in industrial fruit juice with success.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice
AU  - Mauricio Guilherme Vieira
AU  - Gabriel de Souza
AU  - Gilberto Henrique Bardini Aristides
AU  - Larissa Voleck Lopes
AU  - Angélica Machi Lazarin
Y1  - 2017/07/20
PY  - 2017
N1  - https://doi.org/10.11648/j.ijssn.20170502.12
DO  - 10.11648/j.ijssn.20170502.12
T2  - International Journal of Sensors and Sensor Networks
JF  - International Journal of Sensors and Sensor Networks
JO  - International Journal of Sensors and Sensor Networks
SP  - 27
EP  - 33
PB  - Science Publishing Group
SN  - 2329-1788
UR  - https://doi.org/10.11648/j.ijssn.20170502.12
AB  - The chemically modified silica gel with 3-aminopropyltrimethoxysilane groups and EDTA was used to immobilize ruthenium complex initially. These materials were incorporated into a carbon paste electrode and its electrochemical properties were investigated. However, for ascorbic acid solution, an enhancement of the anodic peak current was detected due to electrocatalytic oxidation. The electrodes presented good repeatability, stability and reproducible. The sensors were applied in ascorbic acid determination in industrial fruit juice with success.
VL  - 5
IS  - 2
ER  -

Copy | Download

Author Information

Mauricio Guilherme Vieira

Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil
Gabriel de Souza

Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil
Gilberto Henrique Bardini Aristides

Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil
Larissa Voleck Lopes

Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil
Angélica Machi Lazarin

Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Mauricio Guilherme Vieira, Gabriel de Souza, Gilberto Henrique Bardini Aristides, Larissa Voleck Lopes, Angélica Machi Lazarin. (2017). Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice. International Journal of Sensors and Sensor Networks, 5(2), 27-33. https://doi.org/10.11648/j.ijssn.20170502.12

Copy | Download

ACS Style

Mauricio Guilherme Vieira; Gabriel de Souza; Gilberto Henrique Bardini Aristides; Larissa Voleck Lopes; Angélica Machi Lazarin. Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice. Int. J. Sens. Sens. Netw. 2017, 5(2), 27-33. doi: 10.11648/j.ijssn.20170502.12

Copy | Download

AMA Style

Mauricio Guilherme Vieira, Gabriel de Souza, Gilberto Henrique Bardini Aristides, Larissa Voleck Lopes, Angélica Machi Lazarin. Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice. Int J Sens Sens Netw. 2017;5(2):27-33. doi: 10.11648/j.ijssn.20170502.12

Copy | Download

@article{10.11648/j.ijssn.20170502.12,
  author = {Mauricio Guilherme Vieira and Gabriel de Souza and Gilberto Henrique Bardini Aristides and Larissa Voleck Lopes and Angélica Machi Lazarin},
  title = {Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice},
  journal = {International Journal of Sensors and Sensor Networks},
  volume = {5},
  number = {2},
  pages = {27-33},
  doi = {10.11648/j.ijssn.20170502.12},
  url = {https://doi.org/10.11648/j.ijssn.20170502.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijssn.20170502.12},
  abstract = {The chemically modified silica gel with 3-aminopropyltrimethoxysilane groups and EDTA was used to immobilize ruthenium complex initially. These materials were incorporated into a carbon paste electrode and its electrochemical properties were investigated. However, for ascorbic acid solution, an enhancement of the anodic peak current was detected due to electrocatalytic oxidation. The electrodes presented good repeatability, stability and reproducible. The sensors were applied in ascorbic acid determination in industrial fruit juice with success.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Construction of a New Sensor with Ruthenium Complex Anchored in Functionalized Silica and Their Application in Determination of Ascorbic Acid in Industrial Fruit Juice
AU  - Mauricio Guilherme Vieira
AU  - Gabriel de Souza
AU  - Gilberto Henrique Bardini Aristides
AU  - Larissa Voleck Lopes
AU  - Angélica Machi Lazarin
Y1  - 2017/07/20
PY  - 2017
N1  - https://doi.org/10.11648/j.ijssn.20170502.12
DO  - 10.11648/j.ijssn.20170502.12
T2  - International Journal of Sensors and Sensor Networks
JF  - International Journal of Sensors and Sensor Networks
JO  - International Journal of Sensors and Sensor Networks
SP  - 27
EP  - 33
PB  - Science Publishing Group
SN  - 2329-1788
UR  - https://doi.org/10.11648/j.ijssn.20170502.12
AB  - The chemically modified silica gel with 3-aminopropyltrimethoxysilane groups and EDTA was used to immobilize ruthenium complex initially. These materials were incorporated into a carbon paste electrode and its electrochemical properties were investigated. However, for ascorbic acid solution, an enhancement of the anodic peak current was detected due to electrocatalytic oxidation. The electrodes presented good repeatability, stability and reproducible. The sensors were applied in ascorbic acid determination in industrial fruit juice with success.
VL  - 5
IS  - 2
ER  -

Copy | Download