Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO<sub>3</sub>

G. Benemanskaya; P. Dementev; G. Iluridze; T. Minashvili; G. Frank–Kamenetskaya

doi:doi:10.11648/j.nano.s.2017050301.15

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Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO₃

G. Benemanskaya, P. Dementev, G. Iluridze, T. Minashvili, G. Frank–Kamenetskaya

Published in American Journal of Nano Research and Applications (Volume 5, Issue 3-1)

Received: 6 December 2016 Accepted: 7 December 2016 Published: 6 January 2017

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Abstract

Electronic structure of ceramic BiFeO_3O surface and Ba / BiFeO₃ interface has been investigated in situ in an ultrahigh vacuum via synchrotron-based photoemission spectroscopy within the range of excited photon energy from 120 to 850 eV. The photo emission from the valence band and from Bi 4f, Fe 2p, and Ba 4d core-levels were studied. An effect of Ba atomic layer deposition is found to induce a significant change in all spectra that is originated from the strong interaction with charge transfer between Fe, Bi surface atoms and Ba adatoms. It is obtained that the Fe 2p 3/2 core-level spectrum for the clean BiFeO₃ sample contains both the Fe²⁺ and Fe³⁺ ion components with atomic ratio of Fe²⁺ / Fe³⁺ ~ 1. The Ba adsorption is found to increase the Fe²⁺ / Fe3+ ratio up to ~ 1.5 that clearly exhibits recharge between Fe³⁺ ↔ Fe²⁺ ions and possibility to enhance the ferroelectric polarization.

Published in	American Journal of Nano Research and Applications (Volume 5, Issue 3-1) This article belongs to the Special Issue Nanotechnologies
DOI	10.11648/j.nano.s.2017050301.15
Page(s)	18-21
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Electronic Structure, Surface, Ba / BiFeO₃ Interface, Synchrotron-Photoemission Spectroscopy

References

[1]	L. W. Martin, S. P. Crane, Y.-H. Chu, M. B. Holcomb, M. Gajek, M. Huijben, C.-H. Yang, N. Balke, and R. Ramesh, J. Phys. Condens. Matter, vol. 20, no. 434220, 2008.
[2]	P. Baettig, C. Ederer, and N. A. Spaldin, Phys. Rev. B, vol. 72, no. 214105, 2005.
[3]	J. Li, J. Wang, M. Wuttig, R. Ramesh, N. Wang, B. Ruette, A. P. Pyatakov, A. K. Zvezdin, and D. Viehland, Appl. Phys. Lett., vol. 84, p. 5261, 2004.
[4]	Y. P. Wang, G. L. Yuan, X. Y. Chen, J.-M. Liu, and Z. G. Liu, J. Phys. D, vol. 39, p. 2019, 2006.
[5]	T. Higuchi, Y.-Sh. Liu, P. Yao, P.-A. Glans, J. Guo, Ch. Chang, Z. Wu, W. Sakamoto, N. Itoh, T. Shimura, and T. Yogo, Phys. Rev. B, vol. 78, no. 085106, 2008.
[6]	F. Gao, C. Cai, Y. Wang, S. Dong, X. Y. Qiu, G. L. Yuan, and Z. G. Liu, J. Appl. Phys., vol. 99, no. 094105, 2006.
[7]	S. Mandal, С. K. Ghosh, D. Sarkar, U. N. Maiti, and K. K. Chattopadhyay, Solid State Sci., vol. 12, p. 1803, 2010.
[8]	A. T. Kozakov, A. G. Kochur, K. A. Googlev, A. V. Nikolsky, I. P. Raevski, V. S. Smotrakov, and V. V. Yeremkin, J. Electron Spectrosc. Rel. Phenom., vol. 184, p. 16, 2011.
[9]	I. C. Infante, J. Juraszek, S. Fusil, B. Dupe, P. Gemeiner, O. Dieguez, F. Pailloux, S. Jouen, and E. Jacquet, Phys. Rev. Lett., vol.107, no. 237601, 2011.
[10]	R. Schafranek, J. D. Baniecki, M. Ishii, Y. Kotaka, and K. Kurihara, New J. Phys., vol. 15, no. 053014, 2013.
[11]	J. B. Neaton, C. Ederer, U. V. Waghmare, N. A. Spaldin, and K. M. Rabe, Phys. Rev. B, vol. 71, no. 014113, 2005.
[12]	S. J. Clarkand J. Robertson, Appl. Phys. Lett., vol. 90, no. 132903, 2007.
[13]	K. Liu, H. Fan, P. Ren, and Ch. Yang, J. Alloys Comp., vol. 509, p. 1901, 2011.
[14]	Sh. Li, J. Morasch, A. Klein, Ch. Chirila, L. Pintilie, L. Jia, K. Ellmer, M. Naderer, K. Reichmann, M. Groting, and K. Albe, Phys. Rev. B, vol. 88, no. 045428, 2013.
[15]	B. Ramachandran, A. Dixit, R. Naik, G. Lawes, and M. S. Ramachandra Rao, Phys. Rev. B, vol. 82, no. 012102, 2010.
[16]	Z. V. Gareeva and A. K. Zvezdin, Phys. Status Solidi RRL, vol. 3, p. 79, 2009.
[17]	B. Yu, M. Li, J. Wang, Zh. Hu, X. Liu, Y. Zhu, and X. Zhao, Thin Solid Films, vol. 520, p. 4089, 2012.
[18]	G. V. Benemanskaya, M. N. Lapushkin, and S. N. Timoshnev, Surf. Sci., vol. 603, p. 2474, 2009.
[19]	Y. Jeon, G. Liang, J. Chen, M. Croft, M. W. Ruckman, D. Di. Marzo, and M. S. Hegde, Phys. Rev.B, vol. 41, p. 4066, 1990.

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G. Benemanskaya, P. Dementev, G. Iluridze, T. Minashvili, G. Frank–Kamenetskaya. (2017). Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3. American Journal of Nano Research and Applications, 5(3-1), 18-21. https://doi.org/10.11648/j.nano.s.2017050301.15

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ACS Style

G. Benemanskaya; P. Dementev; G. Iluridze; T. Minashvili; G. Frank–Kamenetskaya. Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3. Am. J. Nano Res. Appl. 2017, 5(3-1), 18-21. doi: 10.11648/j.nano.s.2017050301.15

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AMA Style

G. Benemanskaya, P. Dementev, G. Iluridze, T. Minashvili, G. Frank–Kamenetskaya. Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3. Am J Nano Res Appl. 2017;5(3-1):18-21. doi: 10.11648/j.nano.s.2017050301.15

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@article{10.11648/j.nano.s.2017050301.15,
  author = {G. Benemanskaya and P. Dementev and G. Iluridze and T. Minashvili and G. Frank–Kamenetskaya},
  title = {Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3},
  journal = {American Journal of Nano Research and Applications},
  volume = {5},
  number = {3-1},
  pages = {18-21},
  doi = {10.11648/j.nano.s.2017050301.15},
  url = {https://doi.org/10.11648/j.nano.s.2017050301.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.s.2017050301.15},
  abstract = {Electronic structure of ceramic BiFeO3O surface and Ba / BiFeO3 interface has been investigated in situ in an ultrahigh vacuum via synchrotron-based photoemission spectroscopy within the range of excited photon energy from 120 to 850 eV. The photo emission from the valence band and from Bi 4f,  Fe 2p, and Ba 4d core-levels were studied. An effect of Ba atomic layer deposition is found to induce a significant change in all spectra that is originated from the strong interaction with charge transfer between Fe, Bi surface atoms and Ba adatoms. It is obtained that the Fe 2p 3/2 core-level spectrum for the clean BiFeO3 sample contains both the Fe2+ and Fe3+ ion components with atomic ratio of Fe2+ / Fe3+ ~ 1. The Ba adsorption is found to increase the Fe2+ / Fe3+ ratio up to ~ 1.5 that clearly exhibits recharge between Fe3+ ↔ Fe2+ ions and possibility to enhance the ferroelectric polarization.},
 year = {2017}
}

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TY  - JOUR
T1  - Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3
AU  - G. Benemanskaya
AU  - P. Dementev
AU  - G. Iluridze
AU  - T. Minashvili
AU  - G. Frank–Kamenetskaya
Y1  - 2017/01/06
PY  - 2017
N1  - https://doi.org/10.11648/j.nano.s.2017050301.15
DO  - 10.11648/j.nano.s.2017050301.15
T2  - American Journal of Nano Research and Applications
JF  - American Journal of Nano Research and Applications
JO  - American Journal of Nano Research and Applications
SP  - 18
EP  - 21
PB  - Science Publishing Group
SN  - 2575-3738
UR  - https://doi.org/10.11648/j.nano.s.2017050301.15
AB  - Electronic structure of ceramic BiFeO3O surface and Ba / BiFeO3 interface has been investigated in situ in an ultrahigh vacuum via synchrotron-based photoemission spectroscopy within the range of excited photon energy from 120 to 850 eV. The photo emission from the valence band and from Bi 4f,  Fe 2p, and Ba 4d core-levels were studied. An effect of Ba atomic layer deposition is found to induce a significant change in all spectra that is originated from the strong interaction with charge transfer between Fe, Bi surface atoms and Ba adatoms. It is obtained that the Fe 2p 3/2 core-level spectrum for the clean BiFeO3 sample contains both the Fe2+ and Fe3+ ion components with atomic ratio of Fe2+ / Fe3+ ~ 1. The Ba adsorption is found to increase the Fe2+ / Fe3+ ratio up to ~ 1.5 that clearly exhibits recharge between Fe3+ ↔ Fe2+ ions and possibility to enhance the ferroelectric polarization.
VL  - 5
IS  - 3-1
ER  -

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Author Information

G. Benemanskaya

Department of Solid State Physics, Ioffe Institute, St. Petersburg, Russia
P. Dementev

Department of Solid State Physics, Ioffe Institute, St. Petersburg, Russia
G. Iluridze

Department of Engineering Physics, Georgian Technical University, Tbilisi, Georgia
T. Minashvili

Department of Engineering Physics, Georgian Technical University, Tbilisi, Georgia
G. Frank–Kamenetskaya

Department of Analytical Chemistry, St. Petersburg State Technological Institute, St. Petersburg, Russia

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APA Style

G. Benemanskaya, P. Dementev, G. Iluridze, T. Minashvili, G. Frank–Kamenetskaya. (2017). Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3. American Journal of Nano Research and Applications, 5(3-1), 18-21. https://doi.org/10.11648/j.nano.s.2017050301.15

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ACS Style

G. Benemanskaya; P. Dementev; G. Iluridze; T. Minashvili; G. Frank–Kamenetskaya. Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3. Am. J. Nano Res. Appl. 2017, 5(3-1), 18-21. doi: 10.11648/j.nano.s.2017050301.15

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AMA Style

G. Benemanskaya, P. Dementev, G. Iluridze, T. Minashvili, G. Frank–Kamenetskaya. Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3. Am J Nano Res Appl. 2017;5(3-1):18-21. doi: 10.11648/j.nano.s.2017050301.15

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@article{10.11648/j.nano.s.2017050301.15,
  author = {G. Benemanskaya and P. Dementev and G. Iluridze and T. Minashvili and G. Frank–Kamenetskaya},
  title = {Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3},
  journal = {American Journal of Nano Research and Applications},
  volume = {5},
  number = {3-1},
  pages = {18-21},
  doi = {10.11648/j.nano.s.2017050301.15},
  url = {https://doi.org/10.11648/j.nano.s.2017050301.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.s.2017050301.15},
  abstract = {Electronic structure of ceramic BiFeO3O surface and Ba / BiFeO3 interface has been investigated in situ in an ultrahigh vacuum via synchrotron-based photoemission spectroscopy within the range of excited photon energy from 120 to 850 eV. The photo emission from the valence band and from Bi 4f,  Fe 2p, and Ba 4d core-levels were studied. An effect of Ba atomic layer deposition is found to induce a significant change in all spectra that is originated from the strong interaction with charge transfer between Fe, Bi surface atoms and Ba adatoms. It is obtained that the Fe 2p 3/2 core-level spectrum for the clean BiFeO3 sample contains both the Fe2+ and Fe3+ ion components with atomic ratio of Fe2+ / Fe3+ ~ 1. The Ba adsorption is found to increase the Fe2+ / Fe3+ ratio up to ~ 1.5 that clearly exhibits recharge between Fe3+ ↔ Fe2+ ions and possibility to enhance the ferroelectric polarization.},
 year = {2017}
}

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TY  - JOUR
T1  - Synchrotron-Radiation Photoemission Study of the Ba Atomic Layer Deposition on Multiferroic BiFeO3
AU  - G. Benemanskaya
AU  - P. Dementev
AU  - G. Iluridze
AU  - T. Minashvili
AU  - G. Frank–Kamenetskaya
Y1  - 2017/01/06
PY  - 2017
N1  - https://doi.org/10.11648/j.nano.s.2017050301.15
DO  - 10.11648/j.nano.s.2017050301.15
T2  - American Journal of Nano Research and Applications
JF  - American Journal of Nano Research and Applications
JO  - American Journal of Nano Research and Applications
SP  - 18
EP  - 21
PB  - Science Publishing Group
SN  - 2575-3738
UR  - https://doi.org/10.11648/j.nano.s.2017050301.15
AB  - Electronic structure of ceramic BiFeO3O surface and Ba / BiFeO3 interface has been investigated in situ in an ultrahigh vacuum via synchrotron-based photoemission spectroscopy within the range of excited photon energy from 120 to 850 eV. The photo emission from the valence band and from Bi 4f,  Fe 2p, and Ba 4d core-levels were studied. An effect of Ba atomic layer deposition is found to induce a significant change in all spectra that is originated from the strong interaction with charge transfer between Fe, Bi surface atoms and Ba adatoms. It is obtained that the Fe 2p 3/2 core-level spectrum for the clean BiFeO3 sample contains both the Fe2+ and Fe3+ ion components with atomic ratio of Fe2+ / Fe3+ ~ 1. The Ba adsorption is found to increase the Fe2+ / Fe3+ ratio up to ~ 1.5 that clearly exhibits recharge between Fe3+ ↔ Fe2+ ions and possibility to enhance the ferroelectric polarization.
VL  - 5
IS  - 3-1
ER  -

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