Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth

Christian Grieger; Frank Köster

doi:doi:10.11648/j.sjc.20140202.11

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Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth

Christian Grieger, Frank Köster

Published in Science Journal of Chemistry (Volume 2, Issue 2)

Received: 5 May 2014 Accepted: 22 May 2014 Published: 10 June 2014

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Abstract

Current requirements for measuring applications in biotechnology and biomedical applications require the use of planar sensors or sensor arrays. Previously used techniques for preparing pH-sensitive surfaces have various disadvantages. An interesting alternative is the electroplating of such surfaces. In this work, opportunities for the galvanic deposition of pH-sensitive antimony- and bismuth-layers are presented. The properties of the deposited films in terms of suitability as a pH-sensitive surface are compared. The results indicate that both antimony and bismuth with pH-sensitive layers can be electrodeposited. The separation results can be achieved by varying the parameters and the electrolyte composition influence far reaching. The issue of long-term stability of the deposited layers requires further investigation.

Published in	Science Journal of Chemistry (Volume 2, Issue 2)
DOI	10.11648/j.sjc.20140202.11
Page(s)	6-10
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2014. Published by Science Publishing Group

Keywords

Galvanic Deposition, Antimony, Bismuth, Sensor, Miniaturization, pH-Value

References

[1]	Vonau, W.; Herrmann, S.; Berthold, F.; Enseleit, U.; Bieger, E. P.; Mayer, W.: Multiparameter-Messsystem. Patent Germany 10 2007 022 323.6, 13.11.2008
[2]	Vonau, W. et al.: Elektrochemische Dickschichtsensoren in der Umwelttechnik. GIT Labor-Fachzeitschrift 44 (2000) S. 127-131
[3]	Uhl, A.; Kestranek, W.: Die elektrometrische Titration von Säuren und Basen mit der Antimon-Indikatorelektrode. Monatshefte für Chemie 44 / 1-2 (1923) S. 29-34
[4]	Schwabe, K.: Die pH-Indikation an Wismutelektroden. Zeitschrift für Elektrochemie und angewandte physikalische Chemie 53 (1949) S. 125-132
[5]	Hanzalova, Jitka (Beroun, CZ): A sensing electrode for pH measurement chiefly in bodily fluids. United States 20100116646; 13.05.2010
[6]	Mathers, F. C.; Means, K. S.; Richard, B. F.: Electrodeposition of antimony from fluoride baths containing addition agents. Trans. Am. Electrochem. 31 (1917) S. 293-301
[7]	Harbaugh, M.; Mathers, F. C.: The electrodeposition of bismuth from perchloride acid solutions. Trans. Electrochem. Soc. 64 (1933) S. 293-298
[8]	Krastev, I.; Valkova, T.; Zielonka, A.: Elektrolytische Abscheidung und Eigenschaften von zyklisch modulierten Silber-Wismut-Legierungsüberzügen. Galvanotechnik 96 (2005) S. 1790-1795

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Christian Grieger, Frank Köster. (2014). Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth. Science Journal of Chemistry, 2(2), 6-10. https://doi.org/10.11648/j.sjc.20140202.11

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ACS Style

Christian Grieger; Frank Köster. Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth. Sci. J. Chem. 2014, 2(2), 6-10. doi: 10.11648/j.sjc.20140202.11

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AMA Style

Christian Grieger, Frank Köster. Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth. Sci J Chem. 2014;2(2):6-10. doi: 10.11648/j.sjc.20140202.11

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@article{10.11648/j.sjc.20140202.11,
  author = {Christian Grieger and Frank Köster},
  title = {Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth},
  journal = {Science Journal of Chemistry},
  volume = {2},
  number = {2},
  pages = {6-10},
  doi = {10.11648/j.sjc.20140202.11},
  url = {https://doi.org/10.11648/j.sjc.20140202.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20140202.11},
  abstract = {Current requirements for measuring applications in biotechnology and biomedical applications require the use of planar sensors or sensor arrays. Previously used techniques for preparing pH-sensitive surfaces have various disadvantages. An interesting alternative is the electroplating of such surfaces. In this work, opportunities for the galvanic deposition of pH-sensitive antimony- and bismuth-layers are presented. The properties of the deposited films in terms of suitability as a pH-sensitive surface are compared. The results indicate that both antimony and bismuth with pH-sensitive layers can be electrodeposited. The separation results can be achieved by varying the parameters and the electrolyte composition influence far reaching. The issue of long-term stability of the deposited layers requires further investigation.},
 year = {2014}
}

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TY  - JOUR
T1  - Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth
AU  - Christian Grieger
AU  - Frank Köster
Y1  - 2014/06/10
PY  - 2014
N1  - https://doi.org/10.11648/j.sjc.20140202.11
DO  - 10.11648/j.sjc.20140202.11
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 6
EP  - 10
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20140202.11
AB  - Current requirements for measuring applications in biotechnology and biomedical applications require the use of planar sensors or sensor arrays. Previously used techniques for preparing pH-sensitive surfaces have various disadvantages. An interesting alternative is the electroplating of such surfaces. In this work, opportunities for the galvanic deposition of pH-sensitive antimony- and bismuth-layers are presented. The properties of the deposited films in terms of suitability as a pH-sensitive surface are compared. The results indicate that both antimony and bismuth with pH-sensitive layers can be electrodeposited. The separation results can be achieved by varying the parameters and the electrolyte composition influence far reaching. The issue of long-term stability of the deposited layers requires further investigation.
VL  - 2
IS  - 2
ER  -

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Author Information

Christian Grieger

University of Applied Sciences Mittweida, Technikumplatz 17, D-09648 Mittweida
Frank Köster

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APA Style

Christian Grieger, Frank Köster. (2014). Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth. Science Journal of Chemistry, 2(2), 6-10. https://doi.org/10.11648/j.sjc.20140202.11

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ACS Style

Christian Grieger; Frank Köster. Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth. Sci. J. Chem. 2014, 2(2), 6-10. doi: 10.11648/j.sjc.20140202.11

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AMA Style

Christian Grieger, Frank Köster. Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth. Sci J Chem. 2014;2(2):6-10. doi: 10.11648/j.sjc.20140202.11

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@article{10.11648/j.sjc.20140202.11,
  author = {Christian Grieger and Frank Köster},
  title = {Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth},
  journal = {Science Journal of Chemistry},
  volume = {2},
  number = {2},
  pages = {6-10},
  doi = {10.11648/j.sjc.20140202.11},
  url = {https://doi.org/10.11648/j.sjc.20140202.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20140202.11},
  abstract = {Current requirements for measuring applications in biotechnology and biomedical applications require the use of planar sensors or sensor arrays. Previously used techniques for preparing pH-sensitive surfaces have various disadvantages. An interesting alternative is the electroplating of such surfaces. In this work, opportunities for the galvanic deposition of pH-sensitive antimony- and bismuth-layers are presented. The properties of the deposited films in terms of suitability as a pH-sensitive surface are compared. The results indicate that both antimony and bismuth with pH-sensitive layers can be electrodeposited. The separation results can be achieved by varying the parameters and the electrolyte composition influence far reaching. The issue of long-term stability of the deposited layers requires further investigation.},
 year = {2014}
}

Copy | Download

TY  - JOUR
T1  - Creation of Functional Layers for pH Sensors by Galvanic Deposition of Antimony and Bismuth
AU  - Christian Grieger
AU  - Frank Köster
Y1  - 2014/06/10
PY  - 2014
N1  - https://doi.org/10.11648/j.sjc.20140202.11
DO  - 10.11648/j.sjc.20140202.11
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 6
EP  - 10
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20140202.11
AB  - Current requirements for measuring applications in biotechnology and biomedical applications require the use of planar sensors or sensor arrays. Previously used techniques for preparing pH-sensitive surfaces have various disadvantages. An interesting alternative is the electroplating of such surfaces. In this work, opportunities for the galvanic deposition of pH-sensitive antimony- and bismuth-layers are presented. The properties of the deposited films in terms of suitability as a pH-sensitive surface are compared. The results indicate that both antimony and bismuth with pH-sensitive layers can be electrodeposited. The separation results can be achieved by varying the parameters and the electrolyte composition influence far reaching. The issue of long-term stability of the deposited layers requires further investigation.
VL  - 2
IS  - 2
ER  -

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